从一到百的大写英文表达方式如下：

1. One

2. Two

3. Three

4. Four

5. Five

6. Six

7. Seven

8. Eight

9. Nine

10. Ten

11. Eleven

12. Twelve

13. Thirteen

14. Fourteen

15. Fifteen

16. Sixteen

17. Seventeen

18. Eighteen

19. Nineteen

20. Twenty

21. Twenty-one

22. Twenty-two

23. Twenty-three

24. Twenty-four

25. Twenty-five

26. Twenty-six

27. Twenty-seven

28. Twenty-eight

29. Twenty-nine

30. Thirty

31. Thirty-one

32. Thirty-two

33. Thirty-three

34. Thirty-four

35. Thirty-five

36. Thirty-six

37. Thirty-seven

38. Thirty-eight

39. Thirty-nine

40. Forty

41. Forty-one

42. Forty-two

43. Forty-three

44. Forty-four

45. Forty-five

46. Forty-six

47. Forty-seven

48. Forty-eight

49. Forty-nine

50. Fifty

51. Fifty-one

52. Fifty-two

53. Fifty-three

54. Fifty-four

55. Fifty-five

56. Fifty-six

57. Fifty-seven

58. Fifty-eight

59. Fifty-nine

60. Sixty

61. Sixty-one

62. Sixty-two

63. Sixty-three

64. Sixty-four

65. Sixty-five

66. Sixty-six

67. Sixty-seven

68. Sixty-eight

69. Sixty-nine

70. Seventy

71. Seventy-one

72. Seventy-two

73. Seventy-three

74. Seventy-four

75. Seventy-five

76. Seventy-six

77. Seventy-seven

78. Seventy-eight

79. Seventy-nine

80. Eighty

81. Eighty-one

82. Eighty-two

83. Eighty-three

84. Eighty-four

85. Eighty-five

86. Eighty-six

87. Eighty-seven

88. Eighty-eight

89. Eighty-nine

90. Ninety

91. Ninety-one

92. Ninety-two

93. Ninety-three

94. Ninety-four

95. Ninety-five

96. Ninety-six

97. Ninety-seven

98. Ninety-eight

99. Ninety-nine

100. One hundred

以上是从一到百的大写英文表达方式，可以在日常生活中使用，方便快捷。